PPh3Me[MoBr5(CH3CN)]. IR-Spektrum,magnetisches Verhalten und Kristallstruktur |
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Authors: | Inge Schmidt Jürgen Pebler Ute Patt-Siebel Ulrich Müller Kurt Dehnicke |
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Abstract: | PPh3MeMoBr5(CH3CN)]. I.R. Spectrum, Magnetic Behaviour, and Crystal Structure Molybdenum tetrabromide and acetonitrile form MoBr4(CH3CN)2, from which PPh3MeMoBr5(CH3CN)] is obtained by reaction with PPh3MeBr in dibromo methane. Both compounds are characterized by their IR spectra. By evaluation of the magnetic susceptibility of PPh3MeMoBr5(CH3CN)] in the temperature range of 4.2 to 290 K the Curie-Weiss parameters μcw = 2.65 B.M. and Θ = ?44 K were obtained. The crystal structure of PPh3MeMoBr5(CH3CN)] was determined by X-ray diffraction (2426 observed reflexions, R = 0.082). Crystal data: a = 1064.9, b = 2172.1, c = 1330.4 pm, β = 119.92º, space group P21/c, Z = 4. In the crystal, PPh3Me+ and MoBr5(CH3CN)]? ions are packed in alternate cation and anion layers perpendicular to a. In the anion the Mo atom has a distorted octahedral coordination. The bond length of the bromine atom in trans position to the N atom is considerably shorter than the other MoBr distances. |
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