Abstract: | The First Mixed-valent Oxoplumbate with Isolated Anions. On KNa7PbIVO4]PbIIO3] For the first time KNa7Pb2O7 has been prepared by reaction of K and Na Oxides with ?PbO2”? rsp. PbOred e. g.: KO0.48:NaO0.36:?PbO2”? = 1:7:2 (Ag-cylinders, reduced Ar-pressure, sealed in supremax-glas ampoules, 600°C, 14 d): redorange single crystals of plated shape]. The structure determination 3269 Io(hkl), four-circle diffractometer PW 1100 (Fa. Philips), ω-scan, MoKα, R = 9.52%, Rw = 7.67%, absorption not considered] proves the space group P21/c with a = 1758.48(10), b = 596.76(3), c = 1066.46(8) pm, β = 90.682(8)°, Z = 4, dx = 4.311, dpyk = 4.28 g/cm3. The structure is characterized by isolated PbIVO4] (symmetry nearly Td) and PbIIO3] groups (symmetry nearly C3v), the latter connected by cations to double-layers. The Madelung Part of Lattice Energy, MAPLE, Effective Coordination Numbers, ECoN, these via Mean Fictive Ionic Radii, MEFIR, are calculated and discussed. |