Ein neues Oxozincat: Li6[ZnO4] [1]

A New Oxozincate: Li₆ZnO₄] Colourless single crystals of Li₆ZnO₄] are formed by reaction of Li₂O and ZnO (Li₂O:ZnO = 3.3:1, 700°C 50 d), Space group P4₂/nmc, Z = 2, a = 652.76 pm, c = 465.09 pm R = 2.6%, Rw = 2.1%, 173 symmetry independend I₀(hkl), MoK]. The crystal structure has been determined.