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Synthese und Charakterisierung einer neuen metallacyclisChen Verbindung des Osmiums |
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| Authors: | K. V. Katti H. W. Roesky M. Rietzel |
| Abstract: | Synthesis and Characterization of a New Metallacyclic Compound of Osmium The bissilylated phosphorane, Me3SiNP(Ph2)CH2(Ph2)PNSiMe3 1 reacts with OsO4 via the migration of SiMe3 groups to give a new metallacycle 2 containing OsVIII. 1H, 31P, and 29Si n.m.r. spectroscopic investigations confirm the cyclic structure of 2 . |
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