Abstract: | Investigations about Iodoferrates: The Crystal Structures of Fe(thf)6(FeI3thf)2 · thf and Fe(CH2O)6(FeI4)2 · I2(thf = C4H8O) The crystal structures of FeI2 · 3 thf (i.e. Fe(thf)6(FeI3thf)2 · thf) ( 1 ) and Fe(CH2O)6(FeI4)2 · I2 ( 2 ) were determined from single crystal X-ray data. 1 crystallizes in the cubic space group Pa3, a = 1759.8 pm, Z = 4, 2 in the monoclinic space group P21/n, a = 997.4, b = 1669.4, c = 1082.6 pm, β = 93.11°, Z = 2. The structure of 1 is composed of octahedral Fe(thf)62+ cations and distorted tetrahedral FeI3(thf)]-anions (Fe? I distance 261.1 pm). In 2 two tetrahedral tetraiodoferrate (III) anions are linked by an iodine molecule. The Fe? I distance was found to be 253.9 pm (mean, the I? I distance between FeI4? and I2 356.1 pm. The decomposititon of 1 in vacuum at elevated temperatures and the resulting formation of 2 from 1 are discussed. |