| Abstract: | Reaction of the Two-component System Trialkylphosphite/Carbon Tetrachloride with Nucleophiles. 3. Reaction in Presence of Trialkylammoniumsalts Alkali pseudohalogenides (KSCN, NaN3, KCN) react with the two component system trialkyl phosphite/carbon tetrachloride in presence of trialkylammonium halogenides. Isothiocyanates of dialkylphosphorus acid, N-alkyl phosphoric acid diester amides, N-dialkoxyphosphoryl trialkoxy phosphazenes and tricyano phosphane oxide respectively, are obtained. In the system (RO)3P/CCl4/R3NHI the dialkoxy phosphoryl chloride is formed. |
