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Pyrolysis mechanism of trisbipyridineiron(II) chloride to iron nanoparticles |
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| Authors: | Rabia Nazir Muhammad Mazhar Tehmina Wakeel Muhammad J. Akhtar Muhammad Siddique Muhammad Nadeem Nawazish A. Khan Muhammad R. Shah |
| Affiliation: | 1. Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320, Pakistan 2. Applied Chemistry Research Centre, Pakistan Council of Scientific and Industrial Research Laboratories Complex, Lahore, 54600, Pakistan 3. Department of Chemistry, University of Malaya, Lembah Pantai, 50603, Kuala Lumpur, Malaysia 4. Physics Division, PINSTECH, P.O. Nilore, Islamabad, Pakistan 5. Material Science Laboratory, Department of Physics, Quaid-i-Azam University, Islamabad, 45320, Pakistan 6. HEJ Research Institute of Chemistry, University of Karachi, Karachi, 75270, Pakistan |
| Abstract: | Pyrolysis of trisbipyridineiron(II) chloride under controlled thermal conditions and inert atmosphere of argon gas yields a residue of iron nanoparticles. Evolved gas analysis by GC?CMS and 1H NMR revealed emission of bipyridine, 6-chlorobipyridine, 6,6??-dichlorbipyridine, bipyridine hydrochloride, and hydrochloric acid as decomposition products. CHN, XRPD, EDXRF, TEM, AFM, and 57Fe M?ssbauer spectroscopy of the residue indicated formation of pure iron nanoparticles in the size range of 50?C72?nm. Based on these results a mechanism for thermal degradation of trisbipyridineiron(II) chloride has been worked out. |
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