Total synthesis and properties of prostaglandins 35. Synthesis and properties of 4-carbomethoxy-alkylaminomethylene-(+)2-oxabicyclo[3.3.0]-6-octen-3-ones |
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Authors: | K I Dikovskaya T V Mazur I V Turovskii M P Gavars Ya F Freimanis |
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Institution: | (1) Latvian Institute of Organic Synthesis, LV-1006 Riga |
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Abstract: | Reaction of (+)4-mesyloxymethylene-2-oxabicyclo3.3.0]-6-octen-3-one with -amino acids of different lengths gave (+)4-carbomethoxyalkylaminomethylene-2-oxabicyclo3.3.0]-6-octen-3-ones. For the -aminobutyric ester, the corresponding aminomethylene derivative was obtained both in the linear and the cyclic forms. Acylations of the synthesized enamino lactones by acetyl and benzoyl chlorides were investigated.For Communication 34, see 1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 743–750, June, 1993. |
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