| 过渡金属-碱土金属铜镁异双核配合物的合成、晶体结构和性质研究 |
| |
| 引用本文： | 陶偌偈,臧双全,于兆文. 过渡金属-碱土金属铜镁异双核配合物的合成、晶体结构和性质研究[J]. 无机化学学报, 2002, 18(9): 907-910 |
| |
| 作者姓名： | 陶偌偈 臧双全 于兆文 |
| |
| 作者单位： | 河南大学化学化工学院,开封,475001 |
| |
| 基金项目： | 河南省杰出青年基金资助项目(No.0040301800)，河南省科委基金资助项目(No.211021300)。 |
| |
| 摘 要： | The transition metal and alkaline earth metal heterobinuclear complex[CuMg(TS)(H2O)·H2O],where TS is the schiff base N,N′-bis(3-carboxylsalidene)trimethylenediamine, was synthesised and its crystal structure was determined by the single-crystal X-ray diffraction method at room temperature. It crystallizes in the monoclinic system, space group P21/n. The lattice parameters are a=12.041(2)?, b=14.736(3)?, c=12.062(2)?, β=118.00(3)°, Z=4 with R1=0.0364. The thermal property and EPR studies of the complex according to crystal structure are also investigated. CCDC: 182408.
|
| 关 键 词： | 铜 镁 异双核配合物 热性质 EPR |
| 修稿时间： | 2002-03-02 |
Synthesis, Molecular Structure and Properties of Heterometal Binuclear Complex, [CuMg(TS) (H2O) ]·H2O |
| |
| TAO Ruo-Jie,ZANG Shuang-Quan and YU Zhao-Wen. Synthesis, Molecular Structure and Properties of Heterometal Binuclear Complex, [CuMg(TS) (H2O) ]·H2O[J]. Chinese Journal of Inorganic Chemistry, 2002, 18(9): 907-910 |
| |
| Authors: | TAO Ruo-Jie ZANG Shuang-Quan YU Zhao-Wen |
| |
| Affiliation: | Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001,Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001 and Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001 |
| |
| Abstract: | |
| |
| Keywords: | copper magnesium heterobinuclear complex thermal property EPR |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
|
点击此处可从《无机化学学报》下载全文 |
|
