| C60正丙胺铂,铑配合物的合成及其催化硅氢化性能 |
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| 引用本文： | 方鹏飞 朱绫. C60正丙胺铂,铑配合物的合成及其催化硅氢化性能[J]. 分子催化, 1999, 13(2): 87-92 |
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| 作者姓名： | 方鹏飞 朱绫 |
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| 作者单位： | [1]武汉大学 [2]武汉大学分析测科学系 |
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| 摘 要： | Ｃ６０与正丙胺反应，然后分别与氯亚铂酸钾或三氯化铑配合，制得出含配位氮原子的富勒烯铂，铑 配合物，它们均能有效地催化烯烃与三乙氧基硅烷硅氢加成，铂配合物还对苯乙烯有独特的催化性能，以近１００％的区域选择性得到α－加成产物，对催化机理进行了初步的探讨。
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| 关 键 词： | 富勒烯 硅氢化 催化剂 C60 正丙胺 锗 铑 配合物 |
Synthsis and Catalytic Hydrosilylation Activity of Fullerene n |Propylamine Platinum, Rhodium Complex |
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| FANG Pengfei,CHEN Yuanyin,HU Ling,GUO Lei. Synthsis and Catalytic Hydrosilylation Activity of Fullerene n |Propylamine Platinum, Rhodium Complex[J]. Journal of Molecular Catalysis (China), 1999, 13(2): 87-92 |
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| Authors: | FANG Pengfei CHEN Yuanyin HU Ling GUO Lei |
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| Abstract: | Fullerene n |propylamine platinum and rhodium complexes were prepared by reaction of C60 with n |propylamine, followed by complexing with potassium chloroplatinite or rhodium chloride respectively. These two complexes were effective catalysts for hydrosilylation of olefins with triethoxysilane. The Pt complex exhibited nearly 100% regioselectivety for styrene |adduct. The mechanism of hydrosilylation was also discussed. |
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| Keywords: | Fullerene Hydrosilylation catalyst Regioselectivity Mechanism Studies on Selective Oxidation of C-H Bond Catalyzed by Ruthenium ComplexesYIN Guochuan XI Zuwei CAO Guoying FAN Shuhua HAI Xiaodan (Dalian Institute of Chemical Physics The Chinese A |
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