| C60正丙胺铂,铑配合物的合成及其催化硅氢化性能 |
| |
| 引用本文： | 方鹏飞,朱绫.C60正丙胺铂,铑配合物的合成及其催化硅氢化性能[J].分子催化,1999,13(2):87-92. |
| |
| 作者姓名： | 方鹏飞 朱绫 |
| |
| 作者单位： | [1]武汉大学 [2]武汉大学分析测科学系 |
| |
| 摘 要： | Ｃ６０与正丙胺反应，然后分别与氯亚铂酸钾或三氯化铑配合，制得出含配位氮原子的富勒烯铂，铑 配合物，它们均能有效地催化烯烃与三乙氧基硅烷硅氢加成，铂配合物还对苯乙烯有独特的催化性能，以近１００％的区域选择性得到α－加成产物，对催化机理进行了初步的探讨。
|
| 关 键 词： | 富勒烯 硅氢化 催化剂 C60 正丙胺 锗 铑 配合物 |
Synthsis and Catalytic Hydrosilylation Activity of Fullerene n \|Propylamine Platinum, Rhodium Complex |
| |
| FANG Pengfei,CHEN Yuanyin,HU Ling,GUO Lei.Synthsis and Catalytic Hydrosilylation Activity of Fullerene n \|Propylamine Platinum, Rhodium Complex[J].Journal of Molecular Catalysis (China),1999,13(2):87-92. |
| |
| Authors: | FANG Pengfei CHEN Yuanyin HU Ling GUO Lei |
| |
| Abstract: | Fullerene n \|propylamine platinum and rhodium complexes were prepared by reaction of C60 with n \|propylamine, followed by complexing with potassium chloroplatinite or rhodium chloride respectively. These two complexes were effective catalysts for hydrosilylation of olefins with triethoxysilane. The Pt complex exhibited nearly 100% regioselectivety for styrene \|adduct. The mechanism of hydrosilylation was also discussed. |
| |
| Keywords: | Fullerene Hydrosilylation catalyst Regioselectivity Mechanism Studies on Selective Oxidation of C-H Bond Catalyzed by Ruthenium ComplexesYIN Guochuan XI Zuwei CAO Guoying FAN Shuhua HAI Xiaodan (Dalian Institute of Chemical Physics The Chinese A |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《分子催化》浏览原始摘要信息 |
| 点击此处可从《分子催化》下载免费的PDF全文 |
