| 钌配合物Ru（PA）2Cl对C—H键的选择氧化研究 |
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| 引用本文： | 尹国川 奚祖威. 钌配合物Ru（PA）2Cl对C—H键的选择氧化研究[J]. 分子催化, 1999, 13(2): 93-98 |
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| 作者姓名： | 尹国川 奚祖威 |
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| 作者单位： | 中国科学院大连化学物理研究所 |
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| 基金项目： | 国家高技术863－416－3资助项目 |
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| 摘 要： | 合成了一种新的钌配合物Ｒｕ（ＰＡ）２Ｃｌ，以叔丁基氢化过氧化物为氧源，考察了它对甲苯，乙苯和环己烷的催化氧化反应。发现它对环己烷和乙苯有良好的催化活性。在适当的反应条件下，催化环己烷氧化成环己醇和环己酮，基于产物的催化转化数达１０２１。
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| 关 键 词： | 钌配合物 C－H键 选择氧化 碳氢键 氧化 催经剂 |
Study on the Phase Transfer Catalytic Reduction of Deuterated Acetophone|d8 |
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| ZHANG Lin YOU Dan LIN Bo. Study on the Phase Transfer Catalytic Reduction of Deuterated Acetophone|d8[J]. Journal of Molecular Catalysis (China), 1999, 13(2): 93-98 |
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| Authors: | ZHANG Lin YOU Dan LIN Bo |
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| Affiliation: | ZHANG Lin YOU Dan LIN Bo (Institute of Nuclear Physics and Chemistry The Chinese Academy of Engineering Physics Chengdu 610003) XIE Rugang (Chemistry Department of Si Chuan Union University Chengdu 610064) |
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| Abstract: | Deuterated acetophenone|d8(C6D5|COCD3) was reduced by nickel|aluminum (Ni|Al) alloy in NaOD|D2O solution to give deuterated 1|phenylethanol|d10(C6D5|CDODCD3) in the preseence of phase transfer catalysts (PTC). The reduction procedure was described, and the mechanisms of the phase transfer reduction were proposed. It is found that when 2.5%10% mole ratio of the PTC such as polyethylene glycol (PEG300 or 400), |cyclodextrin ( |CD) and dibenzo|18|crown|6 (DB18C6),is used, the yield of C6D5|CDODCD3 can be increased to more than 90%. |
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| Keywords: | Deuterated acetophenone|d8 Phase transfer catalytic reduction Ni|Al alloy Deuterated 1|phenylethanol|d10 |
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