Heteronuclear Mn-Ca/Sr complexes, and Ca/Sr EXAFS spectral comparisons with the oxygen-evolving complex of photosystem II |
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| Authors: | Mishra Abhudaya Yano Junko Pushkar Yulia Yachandra Vittal K Abboud Khalil A Christou George |
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| Institution: | Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA. |
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| Abstract: | Heterometallic Mn-Ca and Mn-Sr complexes have been prepared and employed as model complexes for Ca and Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); these have revealed similarities that support the presence of at least one O atom bridge between the Mn and Ca/Sr in the OEC. |
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