UV laser-induced photolysis of 1,3-disilacyclobutane in oxygen for chemical vapour deposition of nano-sized polyoxocarbosilane films |
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Authors: | Josef Pola, Josef Ví tek, Zdenk Bastl,Jan ubrt |
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Affiliation: | Josef Pola, Josef Vítek, Zdenk Bastl,Jan ubrt |
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Abstract: | The multi-pulse ArF laser irradiation into gaseous 1,3-disilacyclobutane–O2 mixture in excess of buffer gas occurs as non-explosive chemical vapour deposition of solid methylsilicone films, whereas the single-pulse irradiation into the gaseous mixture in the absence of buffer gas results in explosive chemical vapour deposition of solid nano-structured polyoxocarbosilanes poor in hydrogen. |
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Keywords: | 1,3-Disilacyclobutane Silene Oxidation Laser photolysis Nanostructured polyoxocarbosilane |
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