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UV laser-induced photolysis of 1,3-disilacyclobutane in oxygen for chemical vapour deposition of nano-sized polyoxocarbosilane films
Authors:Josef Pola, Josef Ví  tek, Zdenk Bastl,Jan ubrt
Affiliation:Josef Pola, Josef Vítek, Zden"Image"k Bastl,Jan "Image"ubrt
Abstract:The multi-pulse ArF laser irradiation into gaseous 1,3-disilacyclobutane–O2 mixture in excess of buffer gas occurs as non-explosive chemical vapour deposition of solid methylsilicone films, whereas the single-pulse irradiation into the gaseous mixture in the absence of buffer gas results in explosive chemical vapour deposition of solid nano-structured polyoxocarbosilanes poor in hydrogen.
Keywords:1,3-Disilacyclobutane   Silene   Oxidation   Laser photolysis   Nanostructured polyoxocarbosilane
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