| 一种新颖一维铅碘聚合物[(Pb2I5)(L-H+)·2DMF]n (L=Piperazine)的自组装合成和晶体结构(英) |
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| 引用本文： | 李浩宏,陈之荣,黄长沧,赵斌,肖荣平,倪朝霞.一种新颖一维铅碘聚合物[(Pb2I5)(L-H+)·2DMF]n (L=Piperazine)的自组装合成和晶体结构(英)[J].无机化学学报,2005,21(1):83-86. |
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| 作者姓名： | 李浩宏 陈之荣 黄长沧 赵斌 肖荣平 倪朝霞 |
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| 作者单位： | 福州大学化学化工学院,福州,350002 |
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| 摘 要： | The lead iodide adduct (Pb2I5)(L-H+)·2DMF]n(L=piperazine) has been prepared by self-assembly and structurally characterized. It presents one dimensional structure and crystallizes in Triclinic, P1 space group with the crystal cell parameter: a=0.922 06(18) nm, b=1.237 5(3) nm, c=1.297 2(3) nm, α=99.05(3)°, β=102.98(3)°, γ=105.30(3)°, and V=1.353 8(6) nm3, Z=2, Dc=3.078 Mg·m-3, μ(Mo Kα)=18.127 mm-1, F(000)=1 085, chemical formula C16H43N8O4Pb4I10 and Mr=2 509.39, the final R=0.053 3 and wR=0.146 4 for 3 889 observed reflections with I>2σ(I). CCDC: 250760.
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| 关 键 词： | 配位聚合物 有机-无机杂化 碘化铅 X-射线单晶衍射结构 |
| 收稿时间： | 2004/3/15 0:00:00 |
| 修稿时间： | 2004/8/19 0:00:00 |
The Self-assembly Synthesis and Structure of a Novel 1-D Lead Iodide Adduct: [(Pb2I5)(L-H+)· 2DMF]n (L=Piperazine) |
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| LI Hao-Hong,CHEN Zhi-Rong,HUANG Chang-Cang,ZHAO Bin,XIAO Rong-Ping and NI Zhao-Xia.The Self-assembly Synthesis and Structure of a Novel 1-D Lead Iodide Adduct: [(Pb2I5)(L-H+)· 2DMF]n (L=Piperazine)[J].Chinese Journal of Inorganic Chemistry,2005,21(1):83-86. |
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| Authors: | LI Hao-Hong CHEN Zhi-Rong HUANG Chang-Cang ZHAO Bin XIAO Rong-Ping and NI Zhao-Xia |
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| Institution: | Department of Chemistry, Fuzhou University, Fuzhou 350002,Department of Chemistry, Fuzhou University, Fuzhou 350002,Department of Chemistry, Fuzhou University, Fuzhou 350002,Department of Chemistry, Fuzhou University, Fuzhou 350002,Department of Chemistry, Fuzhou University, Fuzhou 350002 and Department of Chemistry, Fuzhou University, Fuzhou 350002 |
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| Abstract: | The lead iodide adduct (Pb2I5)(L-H+) ·2DMF]n (L=piperazine) has been prepared by self-assembly and structurally characterized. It presents one dimensional structure and crystallizes in Triclinic, P1 space group with the crystal cell parameter: a=0.92206(18) nm, b=1.237 5(3) nm, c=1.297 2(3) nm,α=99.05(3)°, β=102.98(3)°, y=mula C16H43NsO4Pb4I10 and Mr=2 509.39, the final R=0.053 3 and wR=O.146 4 for 3 889 observed reflections with I＞2σ(Ⅰ). CCDC: 250760. |
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| Keywords: | coordination polymers lead iodide organic-inorganic hybrid X-ray single crystal structure |
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