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| 新型不对称酞菁锌的合成和表征 | |
| 引用本文： | 俞孝伟,詹传郎,黄彦.新型不对称酞菁锌的合成和表征[J].有机化学,2012(4):770-775. |
| 作者姓名： | 俞孝伟 詹传郎 黄彦 |
| 作者单位： | 1. 南京工业大学化学化工学院 材料化学工程国家重点实验室 南京210009;中国科学院化学研究所 北京分子科学国家实验室 中国科学院光化学重点实验室 北京100190 2. 中国科学院化学研究所 北京分子科学国家实验室 中国科学院光化学重点实验室 北京100190 3. 南京工业大学化学化工学院 材料化学工程国家重点实验室 南京210009 |
| 摘 要： | 以4-硝基邻苯二甲腈为主要原料,合成了2(3),9(10),16(17),23(24)-四-(正庚酰胺基)-酞菁锌、2(3),9(10),16(17),23(24)-四-(甲氧基)-酞菁锌、2(3),9(10),16(17),23(24)-四-(对叔丁基苯氧基)-酞菁锌和2(3),9(10),16(17),23(24)-四-(苯氧基)-酞菁锌等4种对称型酞菁.在此基础上,选取4-对叔丁基苯氧基邻苯二甲腈为前驱体,采用概率法合成了含有氨基、羧基的2种不对称酞菁锌(A3B). |
| 关 键 词： | 锌酞菁 不对称酞菁 合成 前驱体 概率法 |
Synthesis and Characterization of New Asymmetrical Phthalocyanine Zinc |
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| Yu, Xiaowei , Zhan, Chuanlang , Huang, Yan.Synthesis and Characterization of New Asymmetrical Phthalocyanine Zinc[J].Chinese Journal of Organic Chemistry,2012(4):770-775. | |
| Authors: | Yu Xiaowei Zhan Chuanlang Huang Yan |
| Institution: | Yu,Xiaoweia,b Zhan,Chuanlangb Huang,Yan,a(aState Key Laboratory of Materials-Oriented Chemical Engineering,College of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009)(bBeijing National Laboratory for Molecular Sciences(BNLMS),Laboratory of Photochemistry,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190) |
| Abstract: | Four kinds of symmetrical phthalocyanine zincs(PCZn) 2(3),9(10),16(17),23(24)-(tetraheptanylcarbonyl amino)-phthalocyanine zinc,2(3),9(10),16(17),23(24)-tetramethoxy-phthalocyanine zinc,2(3),9(10),16(17),23(24)-tetra-(4tert-butylphenoxyl)-phthalocyanine zinc,and 2(3),9(10),16(17),23(24)-tetraphenoxyl-phthalocyanine zinc were synthesized from 4-nitro-phthalonitrile.Moreover,the 4-(4-tert-butylphenoxyl)phthalonitrile was employed as a precursor in the synthesis of two kinds of asymmetrical PCZn(A3B) containing either amino-or carboxyl-group by probability method. |
| Keywords: | phthalocyanine zinc asymmetrical phthalocyanine synthesis precursor probability method |
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