| N-(末端三甲基硅苄基甘氨酸肽链)-2,3-萘二甲酰亚胺的光诱导单电子转移成环反应 |
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| 引用本文： | 金英学,王家昌,岳群峰,曲凤玉,魏树权,谭广慧. N-(末端三甲基硅苄基甘氨酸肽链)-2,3-萘二甲酰亚胺的光诱导单电子转移成环反应[J]. 有机化学, 2012, 32(7): 1290-1295 |
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| 作者姓名： | 金英学 王家昌 岳群峰 曲凤玉 魏树权 谭广慧 |
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| 作者单位： | 哈尔滨师范大学化学化工学院 哈尔滨150025 |
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| 基金项目： | 国家自然科学基金，国家自然科学基金，黑龙江省自然科学基金，黑龙江省高校科技创新团队建设计划项目 |
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| 摘 要： | 以苄基甘氨酸为起始物合成了新型分子内给受电子体系N-(末端三甲基硅苄基甘氨酸肽链)-2,3-萘酰亚胺(1).1在MeOH-30%H2O中发生光诱导单电子转移反应,以很高的区域选择性生成新型环苄基甘氨酸肽化合物2.所有新化合物均经MS和NMR确定结构.
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| 关 键 词： | 光诱导 单电子转移 2,3-萘二甲酰亚胺 苄基甘氨酸肽链 环肽 |
Photoinduced Single Electron Transfer Cyclization Reaction of N-(Amidosilane terminated polybenzylglycine peptide chain)-2,3-naphthalimide |
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| Jin,Yingxue , Wang,Jiachang , Yue,Qunfeng , Qu,Fengyu , Wei,Shuquan , Tan,Guanghui. Photoinduced Single Electron Transfer Cyclization Reaction of N-(Amidosilane terminated polybenzylglycine peptide chain)-2,3-naphthalimide[J]. Chinese Journal of Organic Chemistry, 2012, 32(7): 1290-1295 |
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| Authors: | Jin Yingxue Wang Jiachang Yue Qunfeng Qu Fengyu Wei Shuquan Tan Guanghui |
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| Affiliation: | Jin,Yingxue Wang,Jiachang Yue,Qunfeng Qu,Fengyu Wei,Shuquan Tan,Guanghui(College of Chemistry & Engineering,Harbin Normal University,Harbin 150025) |
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| Abstract: | Benzylglycine was used as starting material for the synthesis of novel intramolecular electron donor-accepter system N-(amidosilane terminated polybenzylglycine peptide chain)-2,3-naphthalimide(1).1 could undergo a photoinduced single electron transfer cyclization reaction in MeOH-30% H2O solvent to provide novel cyclopolyglypeptides 2 in high regioselectivity.The structures of all the new compounds were characterized by MS and NMR techniques. |
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| Keywords: | photoinduced single electron transfer 2,3-naphthalimide benzylglycine peptide chain cyclopeptide |
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