Thermodynamic properties of the mixture [x1,3-dioxane+(1-x) 1,4-dioxane] at the temperature 298.15 K |
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Authors: | Takigawa T Tamura K |
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Institution: | (1) Faculty of Engineering, Osaka Institute of Technology, 5-16-1, Ohmiya, Asahi-ku, Osaka 535-8585, Japan;(2) Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan |
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Abstract: | Excess enthalpies, excess heat capacities, excess volumes and sound velocities of the mixture of dioxane isomers, 1,3-dioxane
and 1,4-dioxane, were measured. One of the isomers, 1,4-dioxane is considered as non-polar liquid and the other as polar liquid.
Excess enthalpies are positive and small, less than 55 J mol-1. Excess heat capacities are also very small and the curve is W-shaped, and the values are from 0.03 to -0.08 J mol-1 K-1. Excess volumes and excess isentropic compressibilities are small and positive, and less than 0.03 cm3 mol-1 and 0.8 TPa-1.
This revised version was published online in August 2006 with corrections to the Cover Date. |
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Keywords: | excess heat capacity excess isentropic compressibility excess volume excess enthalpy mixture of dioxane isomers |
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