Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(eta1-OSO)][MeC6H4SO3]2 |
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| Authors: | Bowes Katharine F Cole Jacqueline M Husheer Shamus L G Raithby Paul R Savarese Teresa L Sparkes Hazel A Teat Simon J Warren John E |
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| Institution: | Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW. |
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| Abstract: | The structure of a new metastable geometric isomer of Ru(NH3)4(H2O)(SO2)]MeC6H4SO3]2 in which the SO2 group is coordinated through a single oxygen in an eta1-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp. |
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