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Charge Transfer and Electron Pairing in Fullerenes
Authors:R T Fu  G P Zhang  X Sun  Thomas F George
Institution:(1) Department of Physics, Fudan University, Shanghai, 200433, China;(2) Max-Planck-lnstitut für Mikrostrukturphysik, Weinberg 2, 06120 Halle, Germany;(3) National Laboratory of Infrared Physics, Academia Sinica and Department of Physics, Fudan University, Shanghai, 200433, China;(4) Office of the Chancellor/Departments of Chemistry and Physics & Astronomy, University of Wisconsin-Stevens Point, Stevens Point, Wisconsin, 54481-3897
Abstract:Electron transfer is a common characteristic in fullerene complexes and brings about an optoelectronic effect in a polymer-C60 composite and superconductivity in alkali-metal doped C60. This paper reports that the concept of self-trapping of the transferred electron in C60 can explain the main features of photoinduced electron transfer in a polymer-CC60 composite and electron pairing in alkali-metal doped C60.
Keywords:Fullerenes  electron pairing  charge transfer
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