电场诱导聚合物分子取向对单线态和三线态激子形成截面的影响

通过对聚乙烯咔唑(PVK) 掺杂三(2-苯基吡啶)铱(Ir(ppy)₃)和4-二氰亚甲基-2-叔丁基-6-(1,1,7,7-四甲基久咯呢定基-9-烯基)-4H-吡喃(DCJTB)，PVK 掺杂DCJTB和PVK掺杂Ir(ppy)₃聚合物在成膜时高压电场作用下分子取向变化对单线态和三线态激子形成截面的研究，发现，随着成膜时电场的增强，单线态激子的形成截面在增加，而三线态激子的形成截面却减小. 关键词： 分子取向 激子形成截面 三线态 单线态

The influence of electric field introduced polymer molecular orientation on the formation cross-section of singlet and triplet excitons in PLED

Ir (PPY)₃ and DCJTB doped PVK films were fabricated in the presence of electric field which induced the orientation of polymer molecules, and their photoluminescence and electroluminescence were measured. The influence of electric field-induced orientation on the formation cross-sections of singlet and triplet excitons is investigated. The results showed that the electric field-induced orientation of polymer does not cause significant change in PL spectrum. However, the orientation of polymer results in obvious change in EL spectrum. For the devices based on polarized PVK, the EL from triplet states is reduced, which shows that polarization of PVK leads to the increase in the formation cross-section of singlet exciton and the decrease in the formation of triplet exciton.