Synthesis and potentiometric analysis of organophosphorus metal complexones and complexonates based on 2-aminothiazole derivatives |
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Authors: | L K Sal’keeva A K Shibaeva E K Taishibekova M T Nurmaganbetova E V Minaeva A K Sal’keeva |
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Institution: | 1.Buketov State University,Karaganda,Kazakhstan |
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Abstract: | Synthesis conditions of 4-phenyl-2-amidothiazolyl acetate and 2-thiourido-4-diethylphosphothiazole were developed, and the
complexation capacity of these compounds in formation of mixed-ligand complexes was studied. The optimal conditions and thermodynamic
parameters of the complexation process were determined. The potentiometric method was used to find thermodynamic parameters
of the reactions of mixed-ligand complexation with copper(II) and lead(II) ions, the composition of the complexes being formed
on the basis of 4-phenyl-2-aminothiazole and its phosphorylated derivatives was determined. |
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