Kinetics of I2 and HI photodissociation with implications in flame diagnostics |
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Authors: | Y Zhao C Tong and L Ma |
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Institution: | (1) Department of Organic Chemistry, Moscow State Academy of Fine Chemical Technology, 86 Vernadsky Prospect, Moscow, Russia, 119571;(2) Department of Inorganic Chemistry, Moscow State Academy of Fine Chemical Technology, 86 Vernadsky Prospect, Moscow, Russia, 119571;(3) Department of Chemistry, Moscow State University, Vorob’evy gory, Moscow, Russia, 119992;(4) Frumkin Institute of Physical Chemistry and Electrochemistry, 31 Leninsky Prospect, Moscow, Russia, 119991 |
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Abstract: | This paper investigates the application of iodine (I2) tracer in reactive flows to image the concentration filed by using photodissociation spectroscopy (PDS). The PDS technique
first uses a short laser pulse to completely photodissociate iodine-containing species into iodine atoms, and then uses a
second laser pulse to image the iodine atoms. Due to the completeness and rapidity of the photodissociation (PD), the concentration
of I atoms after PD represents that of the iodine element seeded into the flow, which forms a conserved scalar and can be used to image the concentration field. The feasibility of
the PDS technique is evaluated in three steps. First, a multi-level kinetic model was developed to capture the major physics
relevant to the PDS technique. Second, controlled experiments were conducted to validate the multi-level kinetic model. Third,
the validated model was applied to evaluate the applicable range and accuracy of the PDS technique in representative hydrocarbon
flames. The results suggest a simple approach to implement the PDS technique using I2 seeding in flames, which can provide good accuracy across a wide range of mixture fractions and strain rates. |
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