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Effective synthesis of <Emphasis Type="Italic">N</Emphasis>-substituted 1,3,5-dithiazinanes by reactions of <Emphasis Type="Italic">N</Emphasis>-methyl-1,3,5-dithiazinane and 1,3,5-trithiane with aromatic amines
Authors:E B Rakhimova  I V Vasil’eva  L M Khalilov  A G Ibragimov  U M Dzhemilev
Institution:(1) Department of Chemistry, Faculty of Science and Engineering, Saga University, Saga 840-8502, Japan;(2) Department of Pediatrics, Faculty of Medicine, Saga University, Saga 849-8501, Japan;
Abstract:A novel procedure has been developed for selective synthesis of N-aryl-1,3,5-dithiazinanes, 1,2,6,7-tetrahydro-3,5,1,7-benzodithiadiazonine, and 6,7-dihydro-1,3,5,7-benzotrithiazonine by reactions of aniline derivatives with N-methyl-1,3,5-dithiazinane or 1,3,5-trithiane in the presence of transition and rare earth metal salts and complexes.
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