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Anodic behaviour of mono- and bisdithiafulvenyl-9,9′-spirobifluorene: insertion of vinylogous TTF into the spirobifluorenyle framework |
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| Authors: | Dominique Lorcy Leonardo Mattiello Cyril Poriel Joëlle Rault-Berthelot |
| Abstract: | New three-dimensional copolymers containing 9,9′-spirobifluorenyl-ethylene units were prepared by anodic oxidation of 9,9′-spirobifluorenes 2-mono- or 2,7′-disubstituted by a dithiafulvenyl unit. The synthesis, physicochemical properties and electrochemistry of both monomers and derived oligomers and polymers are reported. |
| Keywords: | Electroactive polymer Spirobifluorene Vinylogous TTF Anodic polymerization |
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