Electrophilic attack on trinuclear titanium imido-nitrido systems |
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| Authors: | Caballo Jorge González-Moreiras Mariano Mena Miguel Pérez-Redondo Adrián Yélamos Carlos |
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| Affiliation: | Departamento de Química Inorgánica, Universidad de Alcalá, 28871 Alcalá de Henares-Madrid, Spain. |
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| Abstract: | Alkylation of [{Ti(η(5)-C(5)Me(5))(μ-NH)}(3)(μ(3)-N)] with MeOTf occurs at the imido ligands to produce the methylamido derivative [Ti(3)(η(5)-C(5)Me(5))(3)(μ(3)-N)(μ-NH)(2)(μ-NHMe)(OTf)] which readily rearranges to form the methylimido complex [Ti(3)(η(5)-C(5)Me(5))(3)(μ(3)-N)(μ-NH)(μ-NH(2))(μ-NMe)(OTf)]. |
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