| 超声强化Keggin型Fe-Mo-Zr杂多酸盐降解染料废水 |
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| 引用本文： | 张治宏,王彩花,王晓昌. 超声强化Keggin型Fe-Mo-Zr杂多酸盐降解染料废水[J]. 化学研究与应用, 2009, 21(4) |
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| 作者姓名： | 张治宏 王彩花 王晓昌 |
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| 作者单位： | 西安建筑科技大学,环境与市政工程学院,陕西,西安,710055;西安工业大学材料与化工学院,陕西,西安,710032;西安建筑科技大学,环境与市政工程学院,陕西,西安,710055;西安科技大学,能源学院,陕西,西安,710054;西安建筑科技大学,环境与市政工程学院,陕西,西安,710055 |
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| 摘 要： | 合成了Fe-Mo-Zr杂多酸盐催化剂,并利用红外光谱(IR)和X射线衍射(XRD)对制得的产物进行了表征,研究了Fe-Mo-Zr杂多酸盐超声降解模拟酸性绿B(AGB)染料废水的效果.结果表明,合成的杂多酸盐具有Keggin型结构,催化剂的投加量、染料的初始浓度及初始pH值、超声频率及超声时间都对降解效果产生一定的影响.当染料浓度为10mg/L,催化剂的投加量为0.6g/L时,在pH为5.0的条件下,用40kHz超声辐射60min,降解率最高可达93.18%.通过动力学分析:降解反应符合一级反应动力学模型,速率常数随初始浓度的增加而减小.
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| 关 键 词： | Fe-Mo-Zr Keggin结构 水处理 超声降解 |
Study on ultrasonic enhanced Fe-Mo-Zr heteropoly salt with keggin structure degradation of dye acidic-green B(AGB) |
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| ZHANG Zhi-hong,WANG Cai-hua,WANG Xiao-chang. Study on ultrasonic enhanced Fe-Mo-Zr heteropoly salt with keggin structure degradation of dye acidic-green B(AGB)[J]. Chemical Research and Application, 2009, 21(4) |
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| Authors: | ZHANG Zhi-hong WANG Cai-hua WANG Xiao-chang |
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| Affiliation: | 1.College of Environmental and Municipal Engineering;Xi'an University of Architecture and Technology;Xi'an 710055;China;2.School of Materials and Chemical Engineering;Xi'an Technological University;Xi'an 710032;3.School of Energy Engineering;Xi'an University of Science and Technology;Xi'an 710054;China |
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| Abstract: | The Fe-Mo-Zr heteropoly salt was synthesized and characterized by IR and XRD.The ultrasonic degradation efficiency of the acidic-green B dye wastewater with Fe-Mo-Zr heteropoly salt was studied.The results showed that the heteropoly salt was Keggin structure.These factors,such as the amount of the heteropoly salt,the initial concentration and the pH value of the acidic-green B dye wastewater,the ultrasonic frequency and the irradiation time,were all effected the degradation efficiency.When the amount of the... |
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| Keywords: | Fe-Mo-Zr |
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