Synthesis and spectral studies on mononuclear complexes of chromium(III) and manganese(II) with 12-membered tetradentate N2O2, N2S2 and N4 donor macrocyclic ligands |
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Authors: | Chandra Sulekh Kumar Rajiv |
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Institution: | (1) Department of Chemistry, Zakir Husain College, University of Delhi, Jawaharlal Nehru Marg, New Delhi, 110002, India |
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Abstract: | Complexes of CrIII and MnII of general formula Cr(L)X2] X and Mn(L)X2] respectively were prepared from N2O2, N2S2 and N4 donor macrocyclic ligands. The complexes have been characterized by elemental analysis, molar conductance measurements, spectral methods (i.r, mass, 1H-n.m.r, electronic spectra and e.p.r.) and magnetic measurements. The macrocyclic ligands have three different donating atom cavities, one with two unsaturated nitrogens and the other two have saturated nitrogen, oxygen and sulphur atoms. The effect of different donor atoms on the spectra and ligand field parameters is discussed. All the complexes show magnetic moments corresponding to a high-spin configuration. On the basis of spectral studies a six coordinated octahedral geometry may be assigned to these complexes. |
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