| 聚钛氨烷-铑络合物催化环己烯的醛化反应 |
| |
| 引用本文： | 袁有学,黄美玉,江英彦.聚钛氨烷-铑络合物催化环己烯的醛化反应[J].高分子学报,1987,0(5):356-358. |
| |
| 作者姓名： | 袁有学 黄美玉 江英彦 |
| |
| 作者单位： | 中国科学院化学研究所 北京
(袁有学，黄美玉)，中国科学院化学研究所 北京(江英彦) |
| |
| 摘 要： | 用聚钛氨烷-铑络合物催化环己烯的醛化,以很高的收率得到了环己基甲醛。
|
| 关 键 词： | 聚钛氨烷-铑络合物 环己烯 醛化反应 |
| 收稿时间： | 1987-04-06 |
HYDROFORMYLATION OF CYCLOHEXENE CATALYZED BY POLYTITAZANE-RHODIUM COMPLEX |
| |
| YUAN You-xue,HUANG Mei-yu,JIANG Ying-yan.HYDROFORMYLATION OF CYCLOHEXENE CATALYZED BY POLYTITAZANE-RHODIUM COMPLEX[J].Acta Polymerica Sinica,1987,0(5):356-358. |
| |
| Authors: | YUAN You-xue HUANG Mei-yu JIANG Ying-yan |
| |
| Institution: | Institute of Chemistry; Academia Sinica; Beijing |
| |
| Abstract: | A new inorganic polymer catalyst, rhodium complex of silica-supported polytitazane (ab-briviated as Ti-N-Rh) has been prepared. It has been found that Ti-N-Rh could catalyze the hydroformylation of cyclohexene at 120℃ and under 60 atm. (CO/H2 = 1), the yield of cyclo-hexyl formaldehyde amouted to 95%. The stability of Ti-N-Rh is very good for the reaction,. and the total turnover numbers amounted to over 20,000. |
| |
| Keywords: | Polytitazane-rhodium Complex Cyclohexene Hydroformylation |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
