Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant |
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| Authors: | Ivan M. Kumanyaev Margarita A. Lapitskaya Ljudmila L. Vasiljeva Kasimir K. Pivnitsky |
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| Affiliation: | N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation |
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| Abstract: | The stable pyridinium salt of o-iodoxybenzoic acid (PIBX) that is easy to obtain can serve as a convenient substitute of IBX as an oxidant. PIBX is safer, has neutral properties behaves as an equivalent to IBX in the oxidation of alcohols to ketones or aldehydes in polar solvents (DMF, DMSO), and provides higher oxidation rate in THF due to better solubility. |
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