Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione |
| |
| Authors: | Nadezhda V Vasilieva Irina G Irtegova Vladimir A Loskutov Leonid A Shundrin |
| |
| Institution: | N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation |
| |
| Abstract: | The electrochemical reduction of benzob]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione in DMSO, MeCN and HMPA is an EE process, which is characterized by two separate one electron reversible peaks on cyclic voltammograms, first peak retains reversibility in DMSO–H2O mixtures, corresponding radical anions were obtained by one electron reduction of the above compounds and characterized by EPR and DFT calculations at the (U)B3LYP/6-31+G* level of theory. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
