H3PW12O40–[bmim][FeCl4]: A novel and green catalyst-medium system for microwave-promoted selective interconversion of alkoxymethyl ethers into their corresponding nitriles, bromides and iodides |
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| Authors: | Iraj Mohammadpoor-Baltork Majid Moghadam Shahram Tangestaninejad Valiolah Mirkhani Arsalan Mirjafari |
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| Institution: | a Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-7344, Iran |
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| Abstract: | In the present work, the catalytic activity of 12-tungstophosphoric acid immobilized on bmim]FeCl4] ionic liquid as a highly efficient and eco-friendly catalytic system for rapid and chemoselective direct conversion of MOM- or EOM-ethers into their corresponding nitriles, bromides and iodides under microwave irradiation is reported. In these reactions, the products are obtained in high yields. The catalyst exhibited remarkable reactivity and was reused several times. |
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| Keywords: | Methoxymethyl ether Interconversion Microwave irradiation H3PW12O40@[bmim][FeCl4] |
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