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Specific thermal and thermodynamic properties of the tellurites Fe2(TeO3)3, Fe2TeO5 and Fe2Te4O11
Authors:G Gospodinov  Lubka Atanasova
Institution:(1) Inorganic Chemical Technology Department, University ‘Prof. Assen Zlatarov’ — Bourgas, 8010 Bourgas, Bulgaria
Abstract:The temperature dependence of the molar heat capacities of the tellurites Fe2(TeO3)3, Fe2TeO5 and Fe2Te4O11 were determined. By statistical manipulation of the values obtained, the parameters in the equations for the corresponding compounds showing this dependence were determined using the least-squares method. These equations together with the standard molar entropies were used to determine the thermodynamic functions Δ0T S m0, ΔTT,H m0 and (Φm0 + Δ0T’ H m0 / T) for T’=298.15 K.
Keywords:iron tellurites  molar heat capacity
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