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Influence of Electron Delocalization on the Magnetic Properties of Iron Ludwigite Fe3O2BO3
Authors:J. J. Larrea  D. R. Sanchez  F. J. Litterst  E. M. Baggio-Saitovitch
Affiliation:1. Centro Brasileiro de Pesquisas Físicas, Rua Dr Xavier Sigaud 150, Rio de Janeiro, 22290-180 RJ, Brazil
2. Institute for Metal Physics and Nuclear Solid State Physics, Technische Universit?t Braunschweig, Mendelssohnstr. 3, D 38106, Braunschweig, Germany
Abstract:57Fe Mössbauer spectroscopic studies of iron ludwigite Fe3O2BO3 performed between 4 and 450 K allow the discussion of magnetic spin arrangements and the dynamics of electronic configurations of iron. The observed magnetic transitions are related to charge ordering.
Keywords:antiferromagnetism  charge order  double exchange  iron oxyborate  M?ssbauer spectroscopy  weak ferromagnetism
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