Vibrational and rotational energy transfers involving the CH B 2Sigma(-) v=1 vibrational level in collisions with Ar, CO, and N2O |
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| Authors: | Huang Hong-Yi Tsai Ming-Tsang Lin King-Chuen |
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| Institution: | Department of Chemistry, National Taiwan University, Taipei 106 and Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan. |
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| Abstract: | With photolysis-probe technique, we have studied vibrational and rotational energy transfers of CH involving the B (2)Sigma(-) (v=1, 0F(1) transitions are larger than the reverse F(1)-->F(2) transitions in DeltaN=0 for the Ar and CO collisions. The trend of fine-structure conservation is along the order of N(2)O
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