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Differences in electronic properties of fluorinated and trifluoromethylated fullerenes revealed by their propensity for dianion formation
Authors:Streletskiy Alexey V  Hvelplund Preben  Nielsen Steen Brøndsted  Liu Bo  Tomita Shigeo  Goryunkov Alexey A  Boltalina Olga V
Institution:Department of Physics and Astronomy, University of Aarhus, DK-8000 Aarhus C, Denmark. lexas@thermo.chem.msu.ru
Abstract:The cross sections for electron transfer from sodium to C(60)F(n) (-) and C(60)(CF(3))(n) (-) anions in 50-keV collisions as a function of the number of functional groups n are reported. There are clear differences between derivatives of fluorine and trifluoromethyl due to the different electron withdrawing properties of F and CF(3). The role of inductive effects and pi electron delocalization on the electron affinity is discussed, assuming a correlation between the cross section and the electron affinity of the anion.
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