Asymmetric halogeno-bridged complexes: new reagents in organometallic synthesis and catalysis |
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| Authors: | Severin Kay |
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| Affiliation: | Institut de Chimie Moléculaire et Biologique Ecole Polytechnique Fédérale de Lausanne, BCH 1015 Lausanne, Switzerland. kay.severin@epfl.ch |
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| Abstract: | Several methods to synthesize bimetallic complexes in which two different metal fragments are connected by halide bridges are described. Using simple starting materials a large pool of structurally defined bimetallic complexes with unique chemical reactivities can be prepared in short time. Applications in organometallic synthesis and homogeneous catalysis are discussed. |
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