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Asymmetric halogeno-bridged complexes: new reagents in organometallic synthesis and catalysis
Authors:Severin Kay
Institution:Institut de Chimie Moléculaire et Biologique Ecole Polytechnique Fédérale de Lausanne, BCH 1015 Lausanne, Switzerland. kay.severin@epfl.ch
Abstract:Several methods to synthesize bimetallic complexes in which two different metal fragments are connected by halide bridges are described. Using simple starting materials a large pool of structurally defined bimetallic complexes with unique chemical reactivities can be prepared in short time. Applications in organometallic synthesis and homogeneous catalysis are discussed.
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