| Synthesis and Properties of Novel Cationic Maleic Diester Polymerizable Surfactants |
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| 引用本文： | Jian XU,Gan Zuo LI*,Guo Wei ZHOU,Fa Ye YAO Key Laboratory for Colloid and Interface Chemistry of State Education Ministry,Shandong University,Jinan 250100. Synthesis and Properties of Novel Cationic Maleic Diester Polymerizable Surfactants[J]. 中国化学快报, 2001, 0(6) |
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| 作者姓名： | Jian XU Gan Zuo LI* Guo Wei ZHOU Fa Ye YAO Key Laboratory for Colloid and Interface Chemistry of State Education Ministry Shandong University Jinan 250100 |
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| 作者单位： | Jian XU，Gan Zuo LI*，Guo Wei ZHOU，Fa Ye YAO Key Laboratory for Colloid and Interface Chemistry of State Education Ministry，Shandong University，Jinan 250100 |
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| 基金项目： | the National Natural Sciences Foundation of China (29903006) and National Microgravity Key Laboratory, Chinese Academy of Scie |
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| 摘 要： | The surfactants used in the emulsion polymerization can be thereafter the source of many problems for the application, such as adhesives and coatings. To overcome these negative aspects essentially related to their mobility in the final polymer, surfactants can be covalently linked to the particle surface through incorporation into the polymer chains. Recent years, polymerizable surfactants (surface active monomer or surfmer) are widely reported and used in the emulsion polymerization, many po…
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Synthesis and Properties of Novel Cationic Maleic Diester Polymerizable Surfactants |
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| Jian XU,Gan Zuo LI,Guo Wei ZHOU,Fa Ye YAO Key Laboratory for Colloid and Interface Chemistry of State Education Ministry,Shandong University,Jinan. Synthesis and Properties of Novel Cationic Maleic Diester Polymerizable Surfactants[J]. Chinese Chemical Letters, 2001, 0(6) |
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| Authors: | Jian XU Gan Zuo LI Guo Wei ZHOU Fa Ye YAO Key Laboratory for Colloid Interface Chemistry of State Education Ministry Shandong University Jinan |
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| Affiliation: | Jian XU,Gan Zuo LI*,Guo Wei ZHOU,Fa Ye YAO Key Laboratory for Colloid and Interface Chemistry of State Education Ministry,Shandong University,Jinan 250100 |
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| Abstract: | Three new cationic polymerizable surfactants are synthesized by the reaction of alkylmaleic hemiester with glycidyltrimethylammonium chloride. Their structures are confirmed by 1H NMR, IR and elements analysis. The values of CMC and (CMC of these surfactants have been measured. One can obtain nearly monodisperse polystyrene latex by emulsion polymerization using the polymerizable surfactant. |
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| Keywords: | Polymerizable surfactant maleic diester surface active monomer surfmer. |
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