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Aromatization of propene on ZSM-5 zeolites
Authors:Z. Popova   K. Aristirova  C. Dimitrov
Affiliation:(1) Faculty of Chemistry, University of Sofia, A. Ivanov, 1, Bulgaria
Abstract:Cu-ZSM-5, CuZn-ZSM-5 and H-ZSM-5 have been studied for propene aromatization at comparable conditions. It was established that all samples are active for aromatization (yields cuesc50%) and demonstrate high selectivity for benzene, toluene and xylenes formation (cuesc 90%). The role of acid centers in all stage of the aromatization is discussed.
Acyrcyocymcyacytcyicyzcyacytscyicyyucy pcyrcyocypcyiecyncyacy ncyacy Cu-ZSM-5, CuZn-ZSM-5 icy H-ZSM-5 icyscyscylcyiecydcyocyvcyacylcyicy vcy pcyocydcyocybcyncyycykhcy ucyscylcyocyvcyicyyacykhcy. Ocybcyrcyacyzcytscyycy tscyiecyocylcyicytcyocyvcy pcyrcyocyyacyvcylcyyacyyucytcy pcyocychcytcyicy ocydcyicyncyacykcyocyvcyucyyucy acykcytcyicyvcyncyocyscytcysoftcy kcy acyrcyocymcyacytcyicyzcyacytscyicyicy (vcyycykhcyocydcy sime 50%) icy ocybcylcyacydcyacyyucytcy vcyycyscyocykcyocyjcy scyiecylcyiecykcytcyicyvcyncyocyscytcysoftcyyucy kcy ocybcyrcyacyzcyocyvcyacyncyicyyucy bcyiecyncyzcyocylcyacy, tcyocylcyucyocylcyacy icy kcyscyicylcyocylcyacy (sime 90%). Ocybcyscyucyzhcydcyacyyucytcy rcyiecyshcyacyyucyshchcyucyyucy rcyocylcysoftcy kcyicyscylcyycykhcy tscyiecyncytcyrcyocyvcy ncyacy vcyscyiecykhcy scytcyucypcyiecyncyyacykhcy acyrcyocymcyacytcyicyzcyacytscyicyicy.
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