Pd(II) conjugated chitosan nanofibre mats for application in Heck cross-coupling reactions |
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| Authors: | Bradshaw Michael Zou Jianli Byrne Lindsay Iyer K Swaminathan Stewart Scott G Raston Colin L |
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| Affiliation: | Centre for Strategic Nano-Fabrication, School of Biomedical, Biomolecular and Chemical Science, The University of Western Australia, Crawley, WA 6009, Australia. |
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| Abstract: | Pd(II)-chitosan composite nanofibres of 62 ± 9 nm diameter are efficient catalysts for Heck cross-coupling reactions. Using a model reaction of iodo-benzene and n-butyl acrylate, we demonstrate that this material can be used as a recyclable catalytic support with a very low loading of palladium (0.17 mol% Pd). |
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