Crystal and Molecular Structure of 1-Methyl-4-(2-( 3,4-dimethoxyphenyl) vinyl) pyridinium 4-Tolylsulfonate Dihydrate C_(16)H_(18)NO_2~+·C_7H_7SO_3~-·2H_2O |
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引用本文: | 彭海静,张天柱,张德纯,张艳秋,郁开北.Crystal and Molecular Structure of 1-Methyl-4-(2-( 3,4-dimethoxyphenyl) vinyl) pyridinium 4-Tolylsulfonate Dihydrate C_(16)H_(18)NO_2~+·C_7H_7SO_3~-·2H_2O[J].结构化学,2001,20(3). |
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作者姓名: | 彭海静 张天柱 张德纯 张艳秋 郁开北 |
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作者单位: | PENG Hai-Jinga ZHANG Tian-Zhub ZHANG De-Chuna ZHANG Yan-Qiua YU Kai-Beic a (Department of Chemistry,Suzhou University,Suzhou 215006,China |
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摘 要: | 1 INTRODUCTIONAs a useful nonlinear optical material, the molecule must have a large second-order hyperpolarizability (β), and also must crystallize in a non-centrosymmetric structure to have a large ((2). Organic conjugated molecules with electronic donors and acceptors possibly have quite strong second-order NLO property. However, only a small percentage of the molecules with large β crystal-lize in useful non-centrosymmetric crystals. Marder and his co-worker carried out a simple an…
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