Partition of carotenoid-to-bacteriochlorophyll singlet-energy transfer through two channels in the LH2 complex from Rhodobacter sphaeroides G1C |
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Authors: | Jian-Ping Zhang Toru Inaba Yasutaka Watanabe Yasushi Koyama |
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Affiliation: | Faculty of Science, Kwansei Gakuin University, Uegahara, Nishinomiya 662–8501, Japan |
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Abstract: | The excited-state dynamics of both carotenoid (Car) and bacteriochlorophyll (BChl) in the LH2 complex from Rhodobacter sphaeroides G1C were simultaneously probed by subpicosecond time-resolved absorption spectroscopy in the visible and near-infrared regions. By the use of a four excited-state model, where the 1Bu+ and 1Bu− states were treated inclusively as the ‘1Bu' state, the time constant and the efficiency partition of Car-to-BChl singlet-energy transfer were determined to be 67–114 fs and 60–74% for the ‘1Bu' channel, and 1.39–1.42 ps and 24–38% for the 2Ag− channel, when a time constant of 170–190 fs was assumed for the 1Bu-to-2Ag− internal conversion. |
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