Fluorinated styrene-based monomers for cyclopolymerizations |
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Authors: | Arvind K. Sharma Dario Pasini |
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Affiliation: | aDepartment of Chemistry, University of Pavia, Via Taramelli, 10 – 27100 Pavia, Italy;bINSTM Research Unit, University of Pavia, Via Taramelli, 10 – 27100 Pavia, Italy |
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Abstract: | The synthesis of versatile fluorine compounds and monomers for conducting polymer research and cyclopolymerizations is presented. Semiprotected 2,3,5,6-tetrafluoroterephthaldehyde 1 could be elaborated through Wittig olefination chemistry, deprotection and reduction to the previously unknown 4-vinyl-2,3,5,6-tetrafluorobenzylalcohol 8 in good yields. Compound 8 can be reacted to form the malonate ester, and then alkylation on the malonate moiety in mild conditions affords difunctional monomer 3. Through sequential esterifications on the malonate moiety, and subsequent alkylation, compound 4, a difunctional monomer for cyclopolymerization bearing one styrene and one perfluoroaryl styrene moiety, has been obtained. Preliminary experiments show that it is possible to cyclopolymerize 4 under free radical conditions. |
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Keywords: | Tetrafluorobenzene derivatives Fluorinated monomers Fluorinated polymers Cyclopolymerization |
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