Diastereoselective synthesis of enantiomeric tertiary alcohols via nucleophilic additions to protected D- and L-erythrulose derivatives期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Diastereoselective synthesis of enantiomeric tertiary alcohols via nucleophilic additions to protected D- and L-erythrulose derivatives

Authors:	Miguel Carda Florenci Gonz lez Santiago Rodrí guez and J Alberto Marco

Institution:	^a Departamento de Ciencias Experimentales, Universitat Jaume l, E-120SO Castellón, Spain ^b Departamento de Quimica Organica, Facultad de Quimicas, Universidad de Valencia, E-46100 Burjassot, Valencia, Spain

Abstract:	The diastereoselectivity of the addition of several organometallic reagents to the carbonyl group of protected - and -erythrulose derivatives has been investigated. Tertiary alcohols are stereoselectively formed, the diastereomeric ratio being markedly dependent on the reagent type, solvent and temperature.

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