| Synthesis and Characterization of Novel Organic／Inorganic Hybrid Polymers Containing Polyhedral Oligosilsesquioxanes |
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| 引用本文： | HongYaoXU XiaoYanGAO ShanYiGUANG FengZhiCHANG. Synthesis and Characterization of Novel Organic／Inorganic Hybrid Polymers Containing Polyhedral Oligosilsesquioxanes[J]. 中国化学快报, 2005, 16(1): 41-44 |
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| 作者姓名： | HongYaoXU XiaoYanGAO ShanYiGUANG FengZhiCHANG |
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| 作者单位： | [1]DepartmentofChemistry,AnhuiUniversity,Anhui230039 [2]DepartmentofChemistry,NationalChiao-TungUniversity,Taiwan |
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| 摘 要： | Hybrid polymers, poly(vinyl pyrrolidone-co-isobutyl styryl polyhedral oligomeric silsesquioxanes)s (PVP-POSS) were synthesized by one step polymerization and characterized using GPC and DSC. Addition of POSS significantly increases the Tg of polyvinylpyrrolidone at a fair high POSS content and obtained high molecular weight polymers with very narrow molecular distribution. The POSS content in the resulted hybrids can be controlled by varying the POSS feed ratio.
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| 关 键 词： | 合成 表征 有机／无机混合聚合体 多面体材料 纳米材料 聚乙烯吡咯烷酮 低硅倍半环氧乙烷 |
Synthesis and Characterization of Novel Organic/Inorganic Hybrid Polymers Containing Polyhedral Oligosilsesquioxanes |
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| Hong Yao XU,Xiao Yan GAO,Shan Yi GUANG,Feng Zhi CHANG. Synthesis and Characterization of Novel Organic/Inorganic Hybrid Polymers Containing Polyhedral Oligosilsesquioxanes[J]. Chinese Chemical Letters, 2005, 16(1): 41-44 |
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| Authors: | Hong Yao XU Xiao Yan GAO Shan Yi GUANG Feng Zhi CHANG |
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| Affiliation: | Hong Yao XU1*,Xiao Yan GAO1,Shan Yi GUANG1,Feng Zhi CHANG2 1Department of Chemistry,Anhui University,Anhui 230039 2Department of Chemistry,National Chiao-Tung University,Taiwan |
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| Abstract: | Hybrid polymers, poly(vinyl pyrrolidone-co-isobutyl styryl polyhedral oligomeric silsesquioxanes)s (PVP-POSS) were synthesized by one step polymerization and characterized using GPC and DSC. Addition of POSS significantly increases the Tg of polyvinylpyrrolidone at a fair high POSS content and obtained high molecular weight polymers with very narrow molecular distribution. The POSS content in the resulted hybrids can be controlled by varying the POSS feed ratio. |
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| Keywords: | Hybrid materials nanocomposites poly(vinylpyrrolidone) polysilsesquioxane. |
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