| CRYSTAL STRUCTURE OF RhCl(dppm)_2·H_2O |
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| 引用本文： | 邵昌平,程国宝,等.CRYSTAL STRUCTURE OF RhCl(dppm)_2·H_2O[J].结构化学,1993,12(5):343-345. |
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| 作者姓名： | 邵昌平 程国宝 等 |
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| 作者单位： | Shao Chang-Ping Cheng Guo-Bao Wang Je-Yu Guo He-FuDalian Institute of Chemical Physics，Chinese Academy of Sciences，Dalian，116023 |
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| 摘 要： | <正> C50H46OP4ClRh, RhCl(dppm)2 · H2O, Mr = 922. 2, monoclinic, P21/2, a=10. 532(3), b=22.574(8), c=18. 641(8) A, β=93. 41(3)°, V = 4424 (3) A3, Z = 4, Dc=1. 386 g. cm-3, λ(MoKα) = 0. 71073A , F(000) = 1904. The structure was determined by direct methods and difference Fourier syntheses and refined by full-matrix least-squares to final R = 0. 037 and Rw = 0. 036 for 3432 (F> 6. 0σ(F) ) observed reflections. The structure of the title compound contains RhCl-(dppm)2 and non-coordinated H2O molecules. The rhodium atom is coordinated by one chlorine atom and four phosphorus atoms of two DPPM ligands forming a tetragonal pyramidal configuration.
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| 关 键 词： | 晶体结构 二（二苯基膦）甲烷 三氯化铑 铑配合物 |
CRYSTAL STRUCTURE OF RhCl(dppm)_2 · H_2O |
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| Shao Chang-Ping Cheng Guo-Bao Wang Je-Yu Guo He-FuDalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian.CRYSTAL STRUCTURE OF RhCl(dppm)_2 · H_2O[J].Chinese Journal of Structural Chemistry,1993,12(5):343-345. |
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| Authors: | Shao Chang-Ping Cheng Guo-Bao Wang Je-Yu Guo He-FuDalian Institute of Chemical Physics Chinese Academy of Sciences Dalian |
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| Institution: | [1]DalianInstituteofChemicalPhysics,ChineseAcademyofS [2]DalianInstituteofChemicalPhys,ChineseAcademyofS |
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| Abstract: | C_(50)H_(46)OP_4ClRh, RhCl(dppm)_2 · H_2O, Mr = 922. 2, monoclinic, P21/2, a=10. 532(3), b=22.574(8), c=18. 641(8) A, β=93. 41(3)°, V = 4424 (3) A3, Z = 4, Dc=1. 386 g. cm-3, λ(MoKα) = 0. 71073A , F(000) = 1904. The structure was determined by direct methods and difference Fourier syntheses and refined by full-matrix least-squares to final R = 0. 037 and Rw = 0. 036 for 3432 (F> 6. 0σ(F) ) observed reflections. The structure of the title compound contains RhCl-(dppm)2 and non-coordinated H2O molecules. The rhodium atom is coordinated by one chlorine atom and four phosphorus atoms of two DPPM ligands forming a tetragonal pyramidal configuration. |
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| Keywords: | crystal structure Rh-Cl-DPPE complex |
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