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Review: Mixed-valent metallodendrimers: design and functions
Authors:Didier Astruc  Amalia Rapakousiou  Yanlan Wang  Rodrigue Djeda  Abdou Diallo  Jaime Ruiz
Affiliation:1. ISM, UMR CNR 5255, Université de Bordeaux, Talence Cedex, Franced.astruc@ism.u-bordeaux1fr;3. ISM, UMR CNR 5255, Université de Bordeaux, Talence Cedex, France
Abstract:Various types of mixed-valent metallodendrimers and star-shaped macromolecules containing ferrocenyl, biferrocenyl, or other redox-robust iron groups with rigid or flexible tethers of short and long lengths mostly studied in the authors’ laboratory including the class type in terms of Robin-Day classification and their functions including electrode modification, sensing, and nanoparticle templates are discussed in this mini review.
Keywords:Dendrimer  Ferrocene  Iron complexes  Mixed valence, Redox  Molecular recognition  Electrostatic effect
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