A low band-gap polymer based on unsubstituted benzo[1,2-b:4,5-b']dithiophene for high performance organic photovoltaics |
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Authors: | Jung Jae Woong Jo Jea Woong Liu Feng Russell Thomas P Jo Won Ho |
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Institution: | WCU Hybrid Materials Program and Department of Materials Science and Engineering, Seoul National University, San 56-1, Shillim-dong, Kwanak-ku, Seoul 151-744, Korea. |
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Abstract: | A low band-gap conjugated polymer, PBDTDPP, composed of unsubstituted benzo1,2-b:4,5-b']dithiophene and diketopyrrolo3,4-c]pyrrole was synthesized. The deep HOMO level of PBDTDPP enhances the V(OC) of a PSC up to 0.82 V and exhibits a PCE of 5.16%, while alkoxy substituted PBDTDPP-OR yields a PCE of 2.24% with a V(OC) of 0.61 V. |
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