Evaluation of Transient Absorption Spectra of N,N,N’,N’—Tetra—(p—methylphenyl) |
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作者姓名: | HePingZeng |
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作者单位: | DepartmentofChemistry,SouthChinaNormalUniversity,Guangzhou510631 |
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摘 要: | Photoinduced electron transfer processes between fullerenes(C60/C70)and N,N,N’,N’-tetra-(p-methylphenyl-4,4’-diamino-1,1’-diphenyl ether(TPDAE)have been studied by nanosecond laser flash photolysis.Quantum yields and rate constants of electron trasfer from TPDAE to excited triplet state of fullerenes(C60/C70)in benzonitrile have been evaluated by observing the trasient absorption bands in the near-IR region where the excited triplet state.radical anion of fullerenes(C60/C70)and radical cations of TPDAE appear.
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关 键 词: | Transient Absorption N N N’ N’-Tetra-(p-methylphenyl-4 4’-diamino-1 1’-diphenyl ether TPDAE 瞬态吸收光谱 |
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